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Your query returned 4 entries. 
Printable version
| EC | 1.3.7.10 | ||
| Transferred entry: | pentalenolactone synthase. Now EC 1.14.19.8, pentalenolactone synthase | ||
| EC | 1.14.11.36 | ||
| Accepted name: | pentalenolactone F synthase | ||
| Reaction: | pentalenolactone D + 2 2-oxoglutarate + 2 O2 = pentalenolactone F + 2 succinate + 2 CO2 + H2O (overall reaction) (1a) pentalenolactone D + 2-oxoglutarate + O2 = pentalenolactone E + succinate + CO2 + H2O (1b) pentalenolactone E + 2-oxoglutarate + O2 = pentalenolactone F + succinate + CO2 |
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| For diagram of pentalenolactone biosynthesis, click here | |||
| Glossary: | pentalenolactone D = (1S,4aR,6aS,9aR)-1,8,8-trimethyl-2-oxo-1,2,4,4a,6a,7,8,9-octahydropentaleno[1,6a-c]pyran-5-carboxylate pentalenolactone E = (4aR,6aS,9aR)-8,8-dimethyl-1-methylene-2-oxo-1,2,4,4a,6a,7,8,9-octahydropentaleno[1,6a-c]pyran-5-carboxylate pentalenolactone F = (1′R,4′aR,6′aS,9′aR)-8′,8′-dimethyl-2′-oxo-4′,4′a,6′a,8′,9′-hexahydrospiro[oxirane-2,1′-pentaleno[1,6a-c]pyran]-5′-carboxylic acid |
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| Other name(s): | penD (gene name); pntD (gene name); ptlD (gene name) | ||
| Systematic name: | pentalenolactone-D,2-oxoglutarate:oxygen oxidoreductase | ||
| Comments: | Requires iron(II) and ascorbate. Isolated from the bacteria Streptomyces exfoliatus, Streptomyces arenae and Streptomyces avermitilis. Part of the pentalenolactone biosynthesis pathway. | ||
| Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc | ||
| References: |
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| EC | 1.14.15.11 | ||
| Accepted name: | pentalenic acid synthase | ||
| Reaction: | 1-deoxypentalenate + reduced ferredoxin + O2 = pentalenate + oxidized ferredoxin + H2O | ||
| For diagram of pentalenolactone biosynthesis, click here | |||
| Glossary: | 1-deoxypentalenate = (1R,3aR,5aS,8aR)-1,7,7-trimethyl-1,2,3,3a,5a,6,7,8-octahydrocyclopenta[c]pentalene-4-carboxylate pentalenate = (1R,3aR,5aS,6R,8aS)-6-hydroxy-1,7,7-trimethyl-1,2,3,3a,5a,6,7,8-octahydrocyclopenta[c]pentalene-4-carboxylate |
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| Other name(s): | CYP105D7; sav7469 (gene name); 1-deoxypentalenate,reduced ferredoxin:O2 oxidoreductase | ||
| Systematic name: | 1-deoxypentalenate,reduced ferredoxin:oxygen oxidoreductase | ||
| Comments: | A heme-thiolate enzyme (P-450). Isolated from the bacterium Streptomyces avermitilis. The product, pentalenate, is a co-metabolite from pentalenolactone biosynthesis. | ||
| Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc, PDB | ||
| References: |
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| EC | 1.14.19.8 | ||
| Accepted name: | pentalenolactone synthase | ||
| Reaction: | pentalenolactone F + O2 + 2 reduced ferredoxin + 2 H+ = pentalenolactone + 2 oxidized ferredoxin + 2 H2O | ||
| For diagram of pentalenolactone biosynthesis, click here | |||
| Glossary: | pentalenolactone F = (1R,4aR,6aS,9aR)-8,8-dimethyl-2-oxo-4,4a,6a,8,9-hexahydrospiro[oxirane-2,1-pentaleno[1,6a-c]pyran]-5-carboxylic acid pentalenolactone = (1R,4aR,6aR,7S,9aS)-7,8-dimethyl-2-oxo-4,4a,6a,7-tetrahydrospiro[oxirane-2,1-pentaleno[1,6a-c]pyran]-5-carboxylic acid |
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| Other name(s): | penM (gene name); pntM (gene name) | ||
| Systematic name: | pentalenolactone-reduced-ferredoxin:oxygen oxidoreductase (pentalenolactone-forming) | ||
| Comments: | A heme-thiolate protein (P-450). Isolated from the bacteria Streptomyces exfoliatus and Streptomyces arenae. | ||
| Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc, PDB | ||
| References: |
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