|
Your query returned 2 entries. Printable version
EC | 1.14.13.217 | ||||
Accepted name: | protodeoxyviolaceinate monooxygenase | ||||
Reaction: | protodeoxyviolaceinate + NAD(P)H + O2 = protoviolaceinate + NAD(P)+ + H2O | ||||
For diagram of violacein biosynthesis, click here | |||||
Glossary: | protodeoxyviolaceinate = 3,5-di(1H-indol-3-yl)-1H-pyrrole-2-carboxylate protoviolaceinate = 5-(5-hydroxy-1H-indol-3-yl)-3-(1H-indol-3-yl)-1H-pyrrole-2-carboxylate |
||||
Other name(s): | vioD (gene name); protoviolaceinate synthase | ||||
Systematic name: | protodeoxyviolaceinate,NAD(P)H:O2 oxidoreductase | ||||
Comments: | The enzyme, characterized from the bacterium Chromobacterium violaceum, participates in the biosynthesis of the violet pigment violacein. The product, protoviolaceinate, can be acted upon by EC 1.14.13.224, violacein synthase, leading to violacein production. However, it is very labile, and in the presence of oxygen can undergo non-enzymic autooxidation to the shunt product proviolacein. | ||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc, PDB | ||||
References: |
| ||||
EC | 1.14.13.224 | ||||
Accepted name: | violacein synthase | ||||
Reaction: | (1) protoviolaceinate + NAD(P)H + O2 = violaceinate + NAD(P)+ + H2O (2) protodeoxyviolaceinate + NAD(P)H + O2 = deoxyviolaceinate + NAD(P)+ + H2O |
||||
For diagram of violacein biosynthesis, click here | |||||
Glossary: | violacein = (3E)-3-[5-(5-hydroxy-1H-indol-3-yl)-2-oxo-1,2-dihydro-3H-pyrrol-3-ylidene]-1,3-dihydro-2H-indol-2-one | ||||
Other name(s): | proviolaceinate monooxygenase; vioC (gene name) | ||||
Systematic name: | protoviolaceinate,NAD(P)H:O2 oxidoreductase | ||||
Comments: | The enzyme, characterized from the bacterium Chromobacterium violaceum, participates in the biosynthesis of the violet pigment violacein. The products, violaceinate and deoxyviolaceinate, undergo non-enzymic autooxidation into violacein and deoxyviolacein, respectively. | ||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc | ||||
References: |
| ||||