Diterpenoids from 9α-copalyl diphosphate

[aphidicolan-16β-ol, 9β-pimara-7,15-diene, stemar-13-ene, stemod-13(17)-ene and momilactone A]

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geranylgeranyl diphosphate biosynthesis
EC 4.2.3.33 stemar-13-ene synthase
EC 4.2.3.34 stemod-13(17)-ene synthase
EC 4.2.3.35 9β-pimara-7,15-diene synthase
EC 4.2.3.42 aphidicolan-16β-ol synthase (mechanism)
EC 4.2.3.99 labdatriene synthase
EC 5.5.1.14 syn-copalyl diphosphate synthase