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Your query returned 1 entry. Printable version
EC | 1.13.11.45 | ||||||
Accepted name: | linoleate 11-lipoxygenase | ||||||
Reaction: | linoleate + O2 = (9Z,12Z)-(11S)-11-hydroperoxyoctadeca-9,12-dienoate | ||||||
Glossary: | arachidonate = (all-Z)-icosa-5,8,11,14-tetraenoate linoleate = (9Z,12Z)-octadeca-9,12-dienoate α-linolenate = (9Z,12Z,15Z)-octadeca-9,12,15-trienoate γ-linolenate = (6Z,9Z,12Z)-octadeca-6,9,12-trienoate oleate = (Z)-octadec-9-enoate |
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Other name(s): | linoleate dioxygenase; manganese lipoxygenase | ||||||
Systematic name: | linoleate:oxygen 11S-oxidoreductase | ||||||
Comments: | The product (9Z,12Z)-(11S)-11-hydroperoxyoctadeca-9,12-dienoate, is converted, more slowly, into (9Z,11E)-(13R)-13-hydroperoxyoctadeca-9,11-dienoate. The enzyme from the fungus Gaeumannomyces graminis requires Mn2+. It also acts on α-linolenate, whereas γ-linolenate is a poor substrate. Oleate and arachidonate are not substrates. | ||||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc, PDB | ||||||
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