| EC |
1.14.13.51 |
| Accepted name: |
6-oxocineole dehydrogenase |
| Reaction: |
6-oxocineole + NADPH + H+ + O2 = 1,6,6-trimethyl-2,7-dioxabicyclo[3.2.2]nonan-3-one + NADP+ + H2O |
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For diagram of 1,8-cineole catabolism, click here |
| Other name(s): |
6-oxocineole oxygenase |
| Systematic name: |
6-oxocineole,NADPH:oxygen oxidoreductase |
| Comments: |
The product undergoes non-enzymic cleavage and subsequent ring closure to form the lactone 4,5-dihydro-5,5-dimethyl-4-(3-oxobutyl)furan-2(3H)-one. |
| Links to other databases: |
BRENDA, EXPASY, KEGG, MetaCyc, CAS registry number: 122933-80-6 |
| References: |
| 1. |
Williams, D.R., Trudgill, P.W. and Taylor, D.G. Metabolism of 1,8-cineole by Rhodococcus species: ring cleavage reactions. J. Gen. Microbiol. 135 (1989) 1957–1967. |
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| [EC 1.14.13.51 created 1992] |
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