| EC |
1.14.13.66 |
| Accepted name: |
2-hydroxycyclohexanone 2-monooxygenase |
| Reaction: |
2-hydroxycyclohexan-1-one + NADPH + H+ + O2 = 6-hydroxyhexan-6-olide + NADP+ + H2O |
| Systematic name: |
2-hydroxycyclohexan-1-one,NADPH:oxygen 2-oxidoreductase (1,2-lactonizing) |
| Comments: |
The product decomposes spontaneously to 6-oxohexanoic acid (adipic semialdehyde). |
| Links to other databases: |
BRENDA, EXPASY, KEGG, MetaCyc, CAS registry number: 62628-31-3 |
| References: |
| 1. |
Davey, J.F. and Trudgill, P.W. The metabolism of trans-cyclohexan-1,2-diol by an Acinetobacter species. Eur. J. Biochem. 74 (1977) 115–127. [DOI] [PMID: 856571] |
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| [EC 1.14.13.66 created 1978 as EC 1.14.12.6, transferred 1999 to EC 1.14.13.66] |
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