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Your query returned 1 entry. Printable version
EC | 1.14.15.13 | ||||
Accepted name: | pulcherriminic acid synthase | ||||
Reaction: | cyclo(L-leucyl-L-leucyl) + 6 reduced ferredoxin + 3 O2 = pulcherriminic acid + 6 oxidized ferredoxin + 4 H2O | ||||
For diagram of cyclic dipeptide biosynthesis, click here | |||||
Glossary: | cyclo(L-leucyl-L-leucyl) = (3S,6S)-3,6-bis(2-methylpropyl)piperazine-2,5-dione pulcherriminic acid = 2,5-dihydroxy-3,6-bis(2-methylpropyl)pyrazine bis-N-oxide |
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Other name(s): | cyclo-L-leucyl-L-leucyl dipeptide oxidase; CYP134A1; CypX (ambiguous) | ||||
Systematic name: | cyclo(L-leucyl-L-leucyl),reduced-ferredoxin:oxygen oxidoreductase (N-hydroxylating,aromatizing) | ||||
Comments: | A heme-thiolate (P-450) enzyme from the bacterium Bacillus subtilis. The order of events during the overall reaction is unknown. Pulcherrimic acid spontaneously forms an iron chelate with Fe(3+) to form the red pigment pulcherrimin [2]. | ||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc, PDB | ||||
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