| EC |
4.2.3.145 |
| Accepted name: |
ophiobolin F synthase |
| Reaction: |
(2E,6E,10E,14E)-geranylfarnesyl diphosphate + H2O = ophiobolin F + diphosphate |
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For diagram of biosynthesis of diterpenoids from ent-copalyl diphosphate, click here and for diagram of sesterterpenoids biosynthesis, click here |
| Systematic name: |
(2E,6E,10E,14E)-geranylfarnesyl-diphosphate diphosphate-lyase (cyclizing, ophiobolin-F-forming) |
| Comments: |
Isolated from the fungus Aspergillus clavatus. The product is a sesterterpenoid (C25 terpenoid). |
| Links to other databases: |
BRENDA, EXPASY, KEGG, MetaCyc |
| References: |
| 1. |
Chiba, R., Minami, A., Gomi, K. and Oikawa, H. Identification of ophiobolin F synthase by a genome mining approach: a sesterterpene synthase from Aspergillus clavatus. Org. Lett. 15 (2013) 594–597. [DOI] [PMID: 23324037] |
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| [EC 4.2.3.145 created 2014] |
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