EC |
4.2.3.178 |
Accepted name: |
stellata-2,6,19-triene synthase |
Reaction: |
(2E,6E,10E,14E)-geranylfarnesyl diphosphate = stellata-2,6,19-triene + diphosphate |
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For diagram of sesterterpenoids biosynthesis, click here |
Glossary: |
stellata-2,6,19-triene = (3S,3aR,5aR,7E,11E,14aR,14bR)-5a,8,12,14b-tetramethyl-3-(prop-1-en-2-yl)-1,2,3,3a,4,5,5a,6,9,10,13,14,14a,14b-tetradecahydrocycloundeca[e]indene |
Systematic name: |
(2E,6E,10E,14E)-geranylfarnesyl-diphosphate diphosphate-lyase (cylizing, stellata-2,6,19-triene-forming) |
Comments: |
Isolated from the fungus Aspergillus stellatus. |
Links to other databases: |
BRENDA, EXPASY, KEGG, MetaCyc |
References: |
1. |
Matsuda, Y., Mitsuhashi, T., Quan, Z. and Abe, I. Molecular basis for stellatic acid biosynthesis: a genome mining approach for discovery of sesterterpene synthases. Org. Lett. 17 (2015) 4644–4647. [DOI] [PMID: 26351860] |
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[EC 4.2.3.178 created 2017] |
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