ExplorEnz: EC 4.2.3.209

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4.2.3.209

Accepted name:

(R)-axinyssene synthase

Reaction:

geranylgeranyl diphosphate = (R)-axinyssene + diphosphate

For diagram of miscellaneous diterpenoid biosynthesis, click here

Glossary:

(R)-axinyssene = (4R)-4-[(5E)-6,10-dimethylundeca-1,5,9-trien-2-yl]-1-methylcyclohexene

Other name(s):

CysTC2

Systematic name:

geranylgeranyl-diphosphate diphosphate-lyase [(R)-axinyssene-forming]

Comments:

Requires Mg²⁺. Characterized from the bacterium Archangium violaceum.

Links to other databases:

BRENDA, EXPASY, KEGG, MetaCyc

References:

1.	Yang, Y.L., Zhang, S., Ma, K., Xu, Y., Tao, Q., Chen, Y., Chen, J., Guo, S., Ren, J., Wang, W., Tao, Y., Yin, W.B. and Liu, H. Discovery and characterization of a new family of diterpene cyclases in bacteria and fungi. Angew. Chem. Int. Ed. Engl. 56 (2017) 4749–4752. [DOI] [PMID: 28371074]

[EC 4.2.3.209 created 2022]