EC |
4.2.3.219 |
Accepted name: |
(2E)-α-cericerene synthase |
Reaction: |
geranylfarnesyl diphosphate = (2E)-α-cericerene + diphosphate |
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For diagram of sesterterpenoids biosynthesis, click here |
Glossary: |
(2E)-α-cericerene = (1E,4R,7E,11E)-1,7,11-trimethyl-4-[(2E)-6-methylhepta-2,5-dien-2-yl]cyclotetrdeca-1,7,11-triene |
Other name(s): |
EvSS |
Systematic name: |
geranylfarneyl-diphosphate diphosphate-lyase (cyclizing, (2E)-α-cericerene-forming) |
Comments: |
A sesterterpenoid synthase enzyme isolated from the fungus Aspergillus stellatus. |
Links to other databases: |
BRENDA, EXPASY, KEGG, MetaCyc |
References: |
1. |
Qin, B., Matsuda, Y., Mori, T., Okada, M., Quan, Z., Mitsuhashi, T., Wakimoto, T. and Abe, I. An unusual chimeric diterpene synthase from Emericella variecolor and its functional conversion into a sesterterpene synthase by domain swapping. Angew. Chem. Int. Ed. Engl. 55 (2016) 1658–1661. [DOI] [PMID: 26546087] |
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[EC 4.2.3.219 created 2023] |
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