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Your query returned 2 entries. Printable version
EC | 1.13.11.83 | ||||||||
Accepted name: | 4-hydroxy-3-prenylphenylpyruvate oxygenase | ||||||||
Reaction: | 3-(4-hydroxy-3-prenylphenyl)pyruvate + O2 = 4-hydroxy-3-prenylmandelate + CO2 | ||||||||
For diagram of 3-dimethylallyl-4-hydroxybenzoate biosynthesis, click here | |||||||||
Glossary: | 3-(4-hydroxy-3-prenylphenyl)pyruvate = 3-(4-hydroxy-3-prenylphenyl)-2-oxopropanoate 4-hydroxy-3-prenylmandelate = 2-hydroxy-2-(4-hydroxy-3-prenylphenyl)acetate prenyl = 3-methylbut-2-en-1-yl |
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Other name(s): | CloR | ||||||||
Systematic name: | 3-(4-hydroxy-3-prenylphenyl)pyruvate:oxygen 1,2-oxidoreductase (4-hydroxy-3-prenylmandelate-forming) | ||||||||
Comments: | Requires non-heme-iron(II). Isolated from the bacterium Streptomyces roseochromogenes DS 12976. A bifunctional enzyme involved in clorobiocin biosynthesis that also catalyses the activity of EC 1.13.12.23, 4-hydroxy-3-prenylbenzoate synthase. | ||||||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc | ||||||||
References: |
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EC | 2.5.1.111 | ||||||||
Accepted name: | 4-hydroxyphenylpyruvate 3-dimethylallyltransferase | ||||||||
Reaction: | prenyl diphosphate + 3-(4-hydroxyphenyl)pyruvate = diphosphate + 3-(4-hydroxy-3-prenylphenyl)pyruvate | ||||||||
For diagram of 3-dimethylallyl-4-hydroxybenzoate biosynthesis, click here and for diagram of 4-hydroxyphenylpyruvate metabolites, click here | |||||||||
Glossary: | 3-dimethylallyl-4-hydroxyphenylpyruvate = 3-[4-hydroxy-3-(3-methylbut-2-en-1-yl)phenyl]-2-oxopropanoate | ||||||||
Other name(s): | CloQ; 4HPP dimethylallyltransferase; NovQ; dimethylallyl diphosphate:4-hydroxyphenylpyruvate 3-dimethylallyltransferase | ||||||||
Systematic name: | prenyl-diphosphate:3-(4-hydroxyphenyl)pyruvate 3′-prenyltransferase | ||||||||
Comments: | The enzyme's product feeds into the biosynthesis of the aminocoumarin antibiotics clorobiocin and novobiocin [1]. | ||||||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc, PDB | ||||||||
References: |
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