The Enzyme Database

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EC 2.7.1.92     
Accepted name: 5-dehydro-2-deoxygluconokinase
Reaction: ATP + 5-dehydro-2-deoxy-D-gluconate = ADP + 6-phospho-5-dehydro-2-deoxy-D-gluconate
For diagram of inositol catabolism, click here
Other name(s): 5-keto-2-deoxygluconokinase; 5-keto-2-deoxyglucono kinase (phosphorylating); DKH kinase
Systematic name: ATP:5-dehydro-2-deoxy-D-gluconate 6-phosphotransferase
Links to other databases: BRENDA, EXPASY, KEGG, MetaCyc, PDB, CAS registry number: 62213-35-8
References:
1.  Anderson, W.A. and Magasanik, B. The pathway of myo-inositol degradation in Aerobacter aerogenes. Conversion of 2-deoxy-5-keto-D-gluconic acid to glycolytic intermediates. J. Biol. Chem. 246 (1971) 5662–5675. [PMID: 4328832]
[EC 2.7.1.92 created 1976]
 
 
EC 4.1.2.29     
Accepted name: 5-dehydro-2-deoxyphosphogluconate aldolase
Reaction: 5-dehydro-2-deoxy-D-gluconate 6-phosphate = glycerone phosphate + malonate semialdehyde
For diagram of inositol catabolism, click here
Glossary: glycerone phosphate = dihydroxyacetone phosphate = 3-hydroxy-2-oxopropyl phosphate
Other name(s): phospho-5-keto-2-deoxygluconate aldolase; 5-dehydro-2-deoxy-D-gluconate-6-phosphate malonate-semialdehyde-lyase
Systematic name: 5-dehydro-2-deoxy-D-gluconate-6-phosphate malonate-semialdehyde-lyase (glycerone-phosphate-forming)
Links to other databases: BRENDA, EXPASY, KEGG, MetaCyc, CAS registry number: 62213-25-6
References:
1.  Anderson, W.A. and Magasanik, B. The pathway of myo-inositol degradation in Aerobacter aerogenes. Conversion of 2-deoxy-5-keto-D-gluconic acid to glycolytic intermediates. J. Biol. Chem. 246 (1971) 5662–5675. [PMID: 4328832]
[EC 4.1.2.29 created 1976]
 
 
EC 5.3.1.30     
Accepted name: 5-deoxy-glucuronate isomerase
Reaction: 5-deoxy-D-glucuronate = 5-dehydro-2-deoxy-D-gluconate
For diagram of inositol catabolism, click here
Glossary: 5-dehydro-2-deoxy-D-gluconate = 2-deoxy-D-threo-hex-5-ulosonic acid
5-deoxy-D-glucuronate = 5-deoxy-D-xylo-hexuronic acid
Other name(s): 5DG isomerase; IolB
Systematic name: 5-deoxy-D-glucuronate aldose-ketose-isomerase
Comments: The enzyme, found in the bacterium Bacillus subtilis, is part of a myo-inositol degradation pathway leading to acetyl-CoA.
Links to other databases: BRENDA, EXPASY, KEGG, MetaCyc
References:
1.  Yoshida, K., Yamaguchi, M., Morinaga, T., Kinehara, M., Ikeuchi, M., Ashida, H. and Fujita, Y. myo-Inositol catabolism in Bacillus subtilis. J. Biol. Chem. 283 (2008) 10415–10424. [DOI] [PMID: 18310071]
[EC 5.3.1.30 created 2014]
 
 


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