The Enzyme Database

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EC 4.2.3.178     
Accepted name: stellata-2,6,19-triene synthase
Reaction: (2E,6E,10E,14E)-geranylfarnesyl diphosphate = stellata-2,6,19-triene + diphosphate
For diagram of sesterterpenoids biosynthesis, click here
Glossary: stellata-2,6,19-triene = (3S,3aR,5aR,7E,11E,14aR,14bR)-5a,8,12,14b-tetramethyl-3-(prop-1-en-2-yl)-1,2,3,3a,4,5,5a,6,9,10,13,14,14a,14b-tetradecahydrocycloundeca[e]indene
Systematic name: (2E,6E,10E,14E)-geranylfarnesyl-diphosphate diphosphate-lyase (cylizing, stellata-2,6,19-triene-forming)
Comments: Isolated from the fungus Aspergillus stellatus.
Links to other databases: BRENDA, EXPASY, KEGG, MetaCyc
References:
1.  Matsuda, Y., Mitsuhashi, T., Quan, Z. and Abe, I. Molecular basis for stellatic acid biosynthesis: a genome mining approach for discovery of sesterterpene synthases. Org. Lett. 17 (2015) 4644–4647. [DOI] [PMID: 26351860]
[EC 4.2.3.178 created 2017]
 
 


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