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Your query returned 2 entries. Printable version
EC | 1.1.1.419 | ||||
Accepted name: | nepetalactol dehydrogenase | ||||
Reaction: | (1) (+)-cis,cis-nepetalactol + NAD+ = (+)-cis,cis-nepetalactone + NADH + H+ (2) (+)-cis,trans-nepetalactol + NAD+ = (+)-cis,trans-nepetalactone + NADH + H+ |
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For diagram of secologanin biosynthesis, click here | |||||
Glossary: | (+)-cis,cis-nepetalactol = (4aR,7S,7aS)-4,7-dimethyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-1-ol (+)-cis,trans-nepetalactol = (+)-iridodial lactol = (4aS,7S,7aR)-4,7-dimethyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-1-ol |
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Other name(s): | NEPS1 (gene name) | ||||
Systematic name: | nepetalactol:NAD+ 1-oxidoreductase | ||||
Comments: | The enzyme, characterized from the plant Nepeta mussinii, binds an NAD+ cofactor. It also catalyses the activity of EC 5.5.1.34, (+)-cis,trans-nepetalactol synthase. | ||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc | ||||
References: |
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EC | 5.5.1.35 | ||||
Accepted name: | (+)-cis,cis-nepetalactol synthase | ||||
Reaction: | (S)-8-oxocitronellyl enol = (+)-cis,cis-nepetalactol | ||||
For diagram of secologanin biosynthesis, click here | |||||
Glossary: | (S)-8-oxocitronellyl enol = (2E,6S,7E)-8-hydroxy-2,6-dimethylocta-2,7-dienal (+)-cis,cis-nepetalactol =(4aR,7S,7aS)-4,7-dimethyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-1-ol |
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Other name(s): | NEPS3 (gene name) | ||||
Systematic name: | (S)-8-oxocitronellyl enol cyclase [(+)-cis,cis-nepetalactol-forming] | ||||
Comments: | The enzyme, characterized from the plant Nepeta mussinii, binds an NAD+ cofactor. The product is a precursor of (+)-cis,cis-nepetalactone, one of the stereoisomers responsible for the psychoactive effects catnip has on cats. | ||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc, PDB | ||||
References: |
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